Not all synthetics are the same.
If you use Mobil 1 5-30 you will probably have a slight drop in oil pressure due to it's viscosity.
If you can find it, I'd reccomend the Mobil 1 0-40, I've switched my LT1 to this and now have slightly higher hot oil pressure.
Your problem is most likely related to your idle. You need a tune to get your idle right and to make sure that your mixture is correct and you aren't washing down the cylinder walls with unburnt fuel.
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Richard
1996 Corvette CE coupe LT1/A4
Mostly stock
1998 Camaro
Z28 badges and dual exhaust tips